Electrochemical Dehydrogenative C(sp 2 )−H Amination
نویسندگان
چکیده
منابع مشابه
H R Csp
A large number of interesting combinatorial optimization problems like M3SAT, MC fall under the class of constraint satisfaction problems. Recent work by one of the authors [34] identifies a semidefinite programming relaxation that yields the optimal approximation ratio for every CSP, under the Unique Games Conjecture. In this work, we present an efficient rounding scheme that achieves th...
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Predicting site selectivity in C-H bond oxidation reactions involving heteroatom transfer is challenged by the small energetic differences between disparate bond types and the subtle interplay of steric and electronic effects that influence reactivity. Herein, the factors governing selective Rh2(esp)2-catalyzed C-H amination of isoamylbenzene derivatives are investigated, where modification to ...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2021
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.202100960